CHE551

Reaction Mechnnisms, Pericyclic Reaction, Photochemistry and Stereo Chemistry
Year / Semester: 
2nd Year

Block I : ORGANIC REACTION MECHANISMS – II                                              
Unit – 1 : Reaction intermediates – I                                                                                  
Unit – 2 : Reaction intermediates – II                                                                                
Unit – 3 : Molecular rearrangements – I                                                                             
Unit – 4 : Molecular rearrangements – II                                                                            
Unit – 5 : Elimination reactions

Block II : PERICYCLIC REACTIONS                                                                        
Unit – 6 : Classification and stereochemistry of pericyclic reactions                                 
Unit – 7 : Molecular orbitals and their symmetry properties                                              
Unit – 8 : Analysis of electrocyclic reactions                                                                     
Unit – 9 : Analysis of cycloaddition reactions
Unit – 10 : Analysis of sigmatropic reactions                                                                     

BLOCK III : ORGANIC PHOTOCHEMISTRY                                                         
Unit – 11 : Electronic transistions
Unit – 12 : Photochemistry of carbonyl compounds                                                          
Unit – 13 : Photochemistry of alkenes and dienes                                                             
Unit – 14 : Photochemistry of benzene derivatives                                                            
Unit – 15 : Photochemistry of peroxides, nitrites, hypohalites, azo compounds and Diazo compounds

BLOCK IV : STEREOCHEMISTRY – II                                                                    
Unit – 16 : Conformations of some acyclic molecules                                                       
Unit – 17 : Conformations of disubstituted cyclohexanes, cyclohexenes and Monosubstituted cyclohexanes
Unit – 18 : Conformation of disubstituted cyclohexanes, cyclohexanes and  Cyclohexanones                                                                                                
Unit – 19 : Conformations of a few other monocyclic and bicyclic systems 

Unit – 20 : Conformation and reactivity